Dezembro 2013 vol. 1 num. 2 - Brazilian Meeting on Organic Synthesis 2013

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Asymmetrical Henry reaction using copper (II)/2-oxazoline complex.

Mello, Murilo B. M. ; Oliveira, Alfredo R. M. ; Ribeiro, and Ronny R. ;

Abstract:

The Henry reaction or nitro aldol reaction is one of the most versatile methods to obtain a new C-C bond. The asymmetric version of this reaction has been used to generate a variety of useful building blocks for organic synthesis. The catalytic asymmetric Henry reaction uses chiral ligands as a source of asymmetry and amino alcohols have found applications as catalysts in asymmetric reactions. Among several asymmetric ligands, several 2-oxazolines derivatives have been used as metal ligands in this type of reaction. In this context, the asymmetrical catalyst copper/2- oxazoline chiral derivative was studied using a new class of chiral 2-oxazoline compounds.

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Palavras-chave: 2-oxazoline, nitro aldol, copper catalyst.,

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DOI: 10.5151/chempro-15bmos-BMOS2013_201391314107

Referências bibliográficas
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Como citar:

Mello, Murilo B. M.; Oliveira, Alfredo R. M.; Ribeiro, and Ronny R.; "Asymmetrical Henry reaction using copper (II)/2-oxazoline complex.", p. 72 . In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 2, Dezembro.2013. São Paulo: Blucher, 2013.
ISSN 2318-4043, DOI 10.5151/chempro-15bmos-BMOS2013_201391314107

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