Blucher Chemistry Proceedings

Junho 2014, vol.2, num.3 - 1st International Seminar on Industrial Innovation in Electrochemistry
Artigo Completo - Open Access Idioma principal | Segundo principal

Electrochemical detection of hydrogen uptake in electrodeposited nickel/nickel hydroxide system to prevent corrosion process

Electrochemical detection of hydrogen uptake in electrodeposited nickel/nickel hydroxide system to prevent corrosion process

Santos, G.A.; Silva, A.G.S.G.; Sanches, L.S.; Ponte; H.A.; Marino, C.E.B.

Artigo Completo:

Brazil has been emphasizing the processing of heavy oils with high corrosivity. This deterioration involved the hydrogen permeation. Electrochemical techniques were used to study the behavior of nickel electrodeposited on a stainless steel during hydrogen charging cycles. The variation of the electrochemical parameters, such as the open-circuit potential indicates the possible presence of hydrogen in the electrodeposited nickel. The XRD analyses show a stable electrode before and after the hydrogen charging cycles. This methodology was efficient for the detection of hydrogen in its early stages of incorporation into the electrode and for the detection of chemical interactions with metallic structures.

Brazil has been emphasizing the processing of heavy oils with high corrosivity. This deterioration involved the hydrogen permeation. Electrochemical techniques were used to study the behavior of nickel electrodeposited on a stainless steel during hydrogen charging cycles. The variation of the electrochemical parameters, such as the open-circuit potential indicates the possible presence of hydrogen in the electrodeposited nickel. The XRD analyses show a stable electrode before and after the hydrogen charging cycles. This methodology was efficient for the detection of hydrogen in its early stages of incorporation into the electrode and for the detection of chemical interactions with metallic structures.

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DOI: 10.5151/chempro-s3ie-08

Referências bibliográficas
  • [1] T Zakroczymski, Electrochim. Acta 51 (2006) 2261.
  • [2] MAV Devanathan, Z Stachurski, The Royal Soc. 270 (1962) 90.
  • [3] K Yamakawa, M Ege, B Ludescher, M Hirscher, H Kronmuller, J. Alloys Comp. 321 (2001) 17.
  • [4] YJ Ouyang, G Yu, AL Ou, L Hu, WJ Xu, Corr. Sci. 53 (2011) 2247.
  • [5] H Addach, P Berçot, M Rezrazi, J Takadoum, Corr. Sci. 51 (2009) 263.
  • [6] C Azevedo, PSA Bezzera, F Esteve, CJBM, Joia, OR Mattos, Electrochim. Acta 4 (1999) 4431.
  • [7] EMK Hillier, MJ Robinson, Corr. Sci. 48 (2005) 1019.
  • [8] M Wu, K Chih, Int. J. Hydrogen Energy 36 (2011) 13407.
  • [9] MAC Domínguez, E Ramirez-Meneses, A Montiel-Palm, AMH Torres, HD Rosalesc, Int. J. Hydrogen Energy 34 (2009) 1664.
  • [10] HW Hoppe, HH. Strehblow, Corr. Sci. 31 (1990) 167.
  • [11] A Seyeux, V Maurice, LH Klein, P Marcus, J. Electrochem. Soc. 153 (2006) B453.
  • [12] CL Fang-Chen, CLY Chen-Qi, Trans. Nonferr. Met. Soc. 17 (2007) 654.
  • [13] K Provazi, MJ Giz, LH Dall´Antonia, SI Córdoba de Torresi, J. Power Sourc. 102 (2001) 224.
  • [14] U. Prakash, N. Parvathavarthini, RK Dayal, Intermetallics 15 (2006) 17.
  • [15] MS Kim, KB Kim, J. Electrochem. Soc. 145 (1998) 507.
  • [16] YW Li, JH Yao, CJ Liu, WM Zhao, WX Deng, SK Zhong, Int. J. Hydrogen Energy 35 (2010) 2539.
  • [17] NV Krstajic, VD Jovic, LJ Gajic-Kjrstajic, BM Jovic, AL Antozzid, GN Martellid, Int. J. Hydrogen Energy 33 (2008) 3676.
  • [18] E Shangguan, H Tang, Z Chang, X Yuan, H Wang, Int. J. Hydrogen Energy 36 (2011) 10057.
  • [19] KD Song, KB Kim, SH Han, S Lee, HK Lee, Electrochem. Comm. 5 (2003) 460.
  • [20] Y Wang, D Cao, G Wang, S Wang, J Wen, J Yin, Electrochim. Acta 56 (2011) 8285.
  • [21] Y Lia, J Yaoa, Y Zhua, Z Zoub, H Wang, J. Power Sourc. 203 (2012) 177.
  • [22] SSM Tavares, S Miraglia, D Fruchart, DS Santos, J. Alloys Comp. 347 (2002) 105.
  • [23] S. Frappart, A. Oudriss, X. Feaugas, J. Creus, J. Bouhattate, F. Thébault, L. Delattre, H. Marchebois, ScriptaMaterialia 65 (2011) 859.
  • [24] L Chao-Qun, L Xin-Hai, W Zhi-Xin, G Hua-Jun, Trans. Nonferr. Metals Soc. China 17 (2007) 1300.
  • [25] A Oudriss, J Creus, J Bouhattate, C Savall, B Peraudeau, X Feaugas, Scripta Materialia 66 (2012) 37.
  • [26] M Monev, Electrochim. Acta. 46 (2001) 2373.
  • [27] J Remigijius, A Selskis, V Kadziauskiene Electrochim. Acta 47 (2002) 13.
  • [28] JT Richardson, R Scates, MV Twigg, App. Cat. A: Gen. 246 (2003) 137.
  • [29] SSM. Tavares, S Miraglia, A Lafuente, D Fruchart, J. Magnet. Mat. 242 (2002) 898.
  • [30] D Kong, J Wang, H Shao, J Zhang, C Cao, J. Alloys Comp. 509 (2011) 5611.
  • [31] A Ul-Hamid, H Dafalla, A Quddus, H Saricimen, LM Al-Hadhrami, Applied Surface Science 257 (2011) 9251.
  • [32] A Godon, J Creus, X Feaugas, E Conforto, L Pichon, C Armand, C Savall, Mat. Charact. 62 (2011) 164.
Como citar:

Santos, G.A.; Silva, A.G.S.G.; Sanches, L.S.; Ponte, ; H.A., ; Marino, C.E.B.; "Electrochemical detection of hydrogen uptake in electrodeposited nickel/nickel hydroxide system to prevent corrosion process", p-65-76. In: In Proceedings of the 1st International Seminar on Industrial Innovation in Electrochemistry [=Blucher Chemistry Proceedings]. São Paulo: Blucher, 2014. São Paulo: Blucher, 2014.
ISSN 23184043, DOI 10.5151/chempro-s3ie-08

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