Fevereiro 2015 vol. 1 num. 2 - XX Congresso Brasileiro de Engenharia Química

Artigo - Open Access.

Idioma principal

ENCAPSULATION OF VEGETABLE OILS BY MINIEMULSION POLYMERIZATION: MATHEMATICAL MODELING

COSTA, C. ; MUSYANOVYCH, A. ; LANDFESTER, K. ; ARAÚJO, P. H. H. ; SAYER, C. ;

Artigo:

Miniemulsion polymerization reactions of MMA were conducted with encapsulation of vegetable oils, using different types (linseed and andiroba oil) and amounts of oils. It was observed a decrease in the reaction rate that was proportional to the number of double bonds present in the oil. Polymers with lower molecular weights were obtained when oils with higher number of double bonds were used. A mathematical model was developed to represent the kinetics of these reactions, including all the other kinetic mechanisms associated to free radical miniemulsion polymerization. The model was able to predict the variation in the polymerization reaction rate depending on the type and amount of the vegetable oil.

Artigo:

Download (PDF)

Palavras-chave:

DOI: 10.5151/chemeng-cobeq2014-1398-19484-143753

Referências bibliográficas
  • [1] BLACK, M.; MESSMAN, J.; RAWLINS, J. Chain Transfer of Vegetable Oil Macromonomers in Acrylic Solution Copolymerization. J. Appl. Polym. Sci., v.120, p.1390-1396, 201
  • [2] CARDOSO, P. B.; ARAUJO, P. H. H.; SAYER, C. Encapsulation of Jojoba and Andiroba Oils by Miniemulsion Polymerization. Effect on Molar Mass Distribution. Macromol. Symp., v.324, p.114-123, 2013.
  • [3] COSTA, C.; TIMMERMANN, S. A. S.; PINTO, J. C; ARAÚJO, P. H. H.; SAYER, C. Compartmentalization Effects on Miniemulsion Polymerization with Oil-soluble Initiator. Macromol. React. Eng., v.7, p.221-231, 201
  • [4] GOOCH, J. W.; DONG, H.; SCHORK, F. J. Waterborne Oil-Modified Polyurethane Coatings via Hybrid Miniemulsion Polymerization. J. Appl. Polym. Sci., v.76, p.105-114, 2000.
  • [5] GUO, J.; SCHORK, F. J. Hybrid Miniemulsion Polymerization of Acrylate/Oil and Acrylate/Fatty Acid Systems. Macromol. React. Eng., v.2, p.265-276, 2008.
  • [6] HUDDA, L.; TSAVALAS, J. G.; SCHORK, F. J. Simulation studies on the origin of the limiting conversion phenomenon in hybrid miniemulsion polymerization. Polymer, v.46, p.993-1001, 2005.
  • [7] LANDFESTER, K. Miniemulsion Polymerization and the Structure of Polymer and Hybrid Nanoparticles. Angew. Chem. Int. Ed., v.48, p.4488-4507, 2009.
  • [8] MELO, M. A. M. F. Avaliação das Propriedades de Óleos Vegetais visando a Produção de Biodiesel. (Dissertação), Departamento de Química, Universidade Federal da Paraíba, João Pessoa, 2010.
  • [9] SAMYN, P.; SCHOUKENS, G.; STANSSENS, D.; VONCK, L.; ABBEELE, H. V. D. Incorporating different vegetable oils into an aqueous dispersion of hybrid organic nanoparticles. J. Nanopart. Res., v.14, p.1075-1099, 2012.
  • [10] TSAVALAS, J. G.; LUO, Y.; SCHORK, F. J. Grafting Mechanisms in Hybrid Miniemulsion Polymerization. J. Appl. Polym. Sci., v.87, p.1825-1836, 2003.
  • [11] USCHANOVA, P.; HEISKANEN, N.; MONONEN, P.; MAUNU, S. L.; KOSKIMIES, S. Synthesis and characterization of tall oil fatty acids-based alkyd resins and alkyd–acrylate copolymers. Prog. Org. Coat., v.63, p.92-99, 2008.
  • [12] WEISS, C. K.; LANDFESTER, K. Miniemulsion Polymerization as a Means to Encapsulate Organic and Inorganic Materials. Adv. Polym. Sci., v.233, p.185-236, 2010.
Como citar:

COSTA, C.; MUSYANOVYCH, A.; LANDFESTER, K.; ARAÚJO, P. H. H.; SAYER, C.; "ENCAPSULATION OF VEGETABLE OILS BY MINIEMULSION POLYMERIZATION: MATHEMATICAL MODELING", p. 12399-12406 . In: Anais do XX Congresso Brasileiro de Engenharia Química - COBEQ 2014 [= Blucher Chemical Engineering Proceedings, v.1, n.2]. São Paulo: Blucher, 2015.
ISSN 2359-1757, DOI 10.5151/chemeng-cobeq2014-1398-19484-143753

últimos 30 dias | último ano | desde a publicação


downloads


visualizações


indexações