Dezembro 2013 vol. 1 num. 2 - Brazilian Meeting on Organic Synthesis 2013

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Further studies on the desymmetrization of cyclic olefins through the Heck-Matsuda arylation

Angnes, Ricardo Almir ; Oliveira, Caio Costa ; Schwalm, Cristiane Storck ; Correia, Carlos Roque Duarte ;

Abstract:

The Matsuda variant of the Heck reaction makes use of arenediazonium salts as arylating partners, which directs the course of the reaction to the so called cationic pathway, claimed to be more reactive and selective. This protocol does not require anhydrous conditions or special atmosphere. The first enantioselective version of this reaction was developed by our group in 2012. Yet many aspects of this reaction remain elusive. This study has as its main objectives the application of new chiral ligands to the catalytic process.

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Palavras-chave: Enantioselective, Heck-Matsuda, Palladium,

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DOI: 10.5151/chempro-15bmos-BMOS2013_2013914221844

Referências bibliográficas
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Como citar:

Angnes, Ricardo Almir; Oliveira, Caio Costa; Schwalm, Cristiane Storck; Correia, Carlos Roque Duarte; "Further studies on the desymmetrization of cyclic olefins through the Heck-Matsuda arylation", p. 249 . In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 2, Dezembro.2013. São Paulo: Blucher, 2013.
ISSN 2318-4043, DOI 10.5151/chempro-15bmos-BMOS2013_2013914221844

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