Setembro 2013 vol. 1 num. 1 - Brazilian Meeting on Organic Synthesis 2011

Abstract - Open Access.

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Influence of microwave irradiation on lipase-catalyzed kinetic resolution of (±)-mandelonitrile

Ribeiro, Sandra S. ; Oliveira, Julieta R. de ; Porto, André L. M. ;

Abstract:

The synthesis of optically pure cyanohydrins is an area of growing interest in synthetic chemistry. Microwave irradiation has also attracted considerable interest in recent years because of their advantages, such as reduced chemical reaction time, reduced side reactions, increased yields and improved reproducibility. The objective of this study was investigate the kinetic resolution of (±)- mandelonitrile (1) using lipase from Candida antarctica under microwave irradiation and conventional conditions.

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Palavras-chave: Enzymatic kinetic resolution, Candida antarctica, Mandelonitrile, Microwave Irradiation,

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DOI: 10.5151/chempro-14bmos-R0291-1

Referências bibliográficas
  • [1] 1Xiong, J.; Wu, J.; Gang, X.; Yang, L. Chem. Eng. J. 2008, 138, 258.
  • [2] 2Bachu, P., Gibson, J. S.; Sperry, J.; Brimble, M. A. Tetrahedron: Asymmetry 2007, 18, 1618.
Como citar:

Ribeiro, Sandra S.; Oliveira, Julieta R. de; Porto, André L. M.; "Influence of microwave irradiation on lipase-catalyzed kinetic resolution of (±)-mandelonitrile", p. 291 . In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 1, Setembro.2013. São Paulo: Blucher, 2013.
ISSN 2318-4043, DOI 10.5151/chempro-14bmos-R0291-1

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