SYNTHESIS AND CHARACTERIZATION OF FeNi ALLOYS NANOPARTICULATE

SYNTHESIS AND CHARACTERIZATION OF FeNi ALLOYS NANOPARTICULATE

dos Santos, C. M.; Martins, A. F. N.; Braga, T. P.; Sasaki, J. M.

Abstract:

Superparamagnetic properties of alloys nanoparticulate have been much studied in recent years due applications in medical and biological areas. This due to the possibility of its use in cancer treatment, vector for transport of drug for the cells and applications as catalysts. The development of new synthetic routes economically viable for synthesis of these materials is of fundamental importance. In this work, the formation of FeNi alloy nanoparticles by the proteic sol-gel method was studied as a function of temperature and reduction flow, and its crystalline characteristics studied by X-ray diffraction associated with Rietveld refinement. Initially, reductions were made in H2 atmosphere with flux of 30 mL/min at several temperatures (500, 600, 650 and 700 °C). Later, the reductions were carried out also in H2 atmosphere, but at a temperature of 500 °C and distinct flow rates (25, 30, 40 and 50 mL/min). Pure alloy was obtained for samples reduced at 650 and 700°C with a flux of 30 mL/min. With respect to variation of the reduced flux, pure alloy was obtained for 40 and 50 mL/min. Rietveld refinement was performed using the GSAS software and interface of EXPGUI, and allowed to determine the microstructural characteristics of the samples. After the crystallographic analysis, we will study magnetic and morphological properties.

Superparamagnetic properties of alloys nanoparticulate have been much studied in recent years due applications in medical and biological areas. This due to the possibility of its use in cancer treatment, vector for transport of drug for the cells and applications as catalysts. The development of new synthetic routes economically viable for synthesis of these materials is of fundamental importance. In this work, the formation of FeNi alloy nanoparticles by the proteic sol-gel method was studied as a function of temperature and reduction flow, and its crystalline characteristics studied by X-ray diffraction associated with Rietveld refinement. Initially, reductions were made in H2 atmosphere with flux of 30 mL/min at several temperatures (500, 600, 650 and 700 °C). Later, the reductions were carried out also in H2 atmosphere, but at a temperature of 500 °C and distinct flow rates (25, 30, 40 and 50 mL/min). Pure alloy was obtained for samples reduced at 650 and 700°C with a flux of 30 mL/min. With respect to variation of the reduced flux, pure alloy was obtained for 40 and 50 mL/min. Rietveld refinement was performed using the GSAS software and interface of EXPGUI, and allowed to determine the microstructural characteristics of the samples. After the crystallographic analysis, we will study magnetic and morphological properties.

Palavras-chave:

DOI: 10.5151/phypro-sic100-039

Como citar:

dos Santos, C. M.; Martins, A. F. N.; Braga, T. P.; Sasaki, J. M.; "SYNTHESIS AND CHARACTERIZATION OF FeNi ALLOYS NANOPARTICULATE", p-39-39. In: Proceedings of the International Symposium on Crystallography [Blucher Physics Proceedings, v.1, n.3]. São Paulo: Blucher, 2015.
ISSN 23582359, DOI 10.5151/phypro-sic100-039