Setembro 2013 vol. 1 num. 1 - Brazilian Meeting on Organic Synthesis 2011

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Synthesis of the C5-C17 fragment of saliniketal A

Perez, Carla Cristina ; Dias, Luiz Carlos ;

Abstract:

The marine-derived saliniketals A (1) and B (2) were isolated from the marine actinomycete Salinispora arenicola by Fenical and co-workers. Their structures were confirmed by total synthesis in 2007. We wish to describe here our synthetic strategy for the synthesis of saliniketal A.

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Palavras-chave: saliniketal, polyketides, ornithine decarboxylase,

Palavras-chave: ,

DOI: 10.5151/chempro-14bmos-R0109-1

Referências bibliográficas
  • [1] 1 (a) Willian, P.G.; Asolkar, R.N.; Kondratyuk, T.; Pezzuto, J.M.; Jensen, P.R.; Fenical, W. J. Nat. Prod. 2007, 70, 83-88. (b) Paterson, I.; Razzak. M.; Anderson, E.A. Org. Lett. 2008, 10, 3295-3298
  • [2] 2 Matsomuri, N.; Kaneno, D.; Murata, M.; Nakamura, H.; Tachibama, K. J. Org. Chem. 1999, 64, 866-876.
  • [3] 3 The measurement of coupling constants nJCH were made using HSQC-TOCSY-IPAP experiments in collaboration with Professor Cláudio Tormena at Unicamp.
  • [4] 4 Parella, T.; Belloc, J.; Sánchez-Ferrando, F.; Virgili, A. Magn. Reson. Chem. 1998, 36, 715 – 719.
  • [5] 5 Rychnovsky, S.D.; Skalitzky, D.J. Tetrahedron Lett. 1990, 31, 94
Como citar:

Perez, Carla Cristina; Dias, Luiz Carlos; "Synthesis of the C5-C17 fragment of saliniketal A", p. 109 . In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 1, Setembro.2013. São Paulo: Blucher, 2013.
ISSN 2318-4043, DOI 10.5151/chempro-14bmos-R0109-1

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