Setembro 2013 vol. 1 num. 1 - Brazilian Meeting on Organic Synthesis 2011

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Synthetic studies towards the elucidation of the stereochemistry of compounds of the Cryptomoscatone D family

Drekener, Roberta L. ; Pilli, Ronaldo A. ;

Abstract:

Natural compounds of the 5,6-dihydropyranone family, isolated from the genus Cryptocarya (Laureacae), have attracted scientific interest due to their biological activities. Among these compounds, we highlight Cryptomoscatone D1 and D2, isolated from C. mandiocanna, for which a definitive proof of structure is still lacking. In this work, we describe our synthetic efforts toward compounds 1 and 2 in order to contribute to the elucidation of the stereochemistry of Criptomoscatones D1 and D2 (Figure 1).

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Palavras-chave: cryptomoscatone, Keck’s allylation, 1, 5-anti aldol,

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DOI: 10.5151/chempro-14bmos-R0094-1

Referências bibliográficas
  • [1] 1 Cossy, J.; BouzBouz, S. Org. Lett. 2003, 5, 1995.
  • [2] 2 Cavalheiro, A. J.; Yoshida, M. Phytochemistry 2000, 53, 811.
  • [3] 3 Narasaka, K.; Pai, F. -C. Tetrahedron 1984, 40, 223
  • [4] 4 Evans, D. A.; Chapman, K. T. Tetrahedron Lett. 1986, 27, 5939.
Como citar:

Drekener, Roberta L.; Pilli, Ronaldo A.; "Synthetic studies towards the elucidation of the stereochemistry of compounds of the Cryptomoscatone D family", p. 94 . In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 1, Setembro.2013. São Paulo: Blucher, 2013.
ISSN 2318-4043, DOI 10.5151/chempro-14bmos-R0094-1

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