An experimental and theoretical study of the cycloaddition reactions of carbomethoxy-para-benzoquinones with 6,6-dimethyl-fulvene

An experimental and theoretical study of the cycloaddition reactions of carbomethoxy-para-benzoquinones with 6,6-dimethyl-fulvene

Servilha, Bruno M.; Donatoni, Maria C.; Oliveira, Kleber T. de; Ferreira, Marco A. B.; Brocksom, Timothy J.

Abstract:

The Diels-Alder reactions of non-symmetric parabenzoquinones with simple dienes can furnish promising intermediates for the synthesis of bioactive natural products. We now present our results on the Diels-Alder reactions of 6,6-dimethylfulvene and carbomethoxy-substituted parabenzoquinones. DFT calculations were also performed for the reactions reported herein.

The Diels-Alder reactions of non-symmetric parabenzoquinones with simple dienes can furnish promising intermediates for the synthesis of bioactive natural products. We now present our results on the Diels-Alder reactions of 6,6-dimethylfulvene and carbomethoxy-substituted parabenzoquinones. DFT calculations were also performed for the reactions reported herein.

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DOI: 10.5151/chempro-15bmos-BMOS2013_20139416531

Referências bibliográficas

• [1] 1 Brocksom, T. J.; et. al. “Diels-Alder Reactions in the Synthesis of Higher Terpenes,” in Organic Synthesis: Theory and
• [2] Applications, T. Hudlicky (ed). JAI/Elsevier, Vol. 5, 39-87, 2001.

Como citar:

Servilha, Bruno M.; Donatoni, Maria C.; Oliveira, Kleber T. de; Ferreira, Marco A. B.; Brocksom, Timothy J.; "An experimental and theoretical study of the cycloaddition reactions of carbomethoxy-para-benzoquinones with 6,6-dimethyl-fulvene", p-20-20. In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 2, Dezembro.2013. São Paulo: Blucher, 2013.
ISSN 23184043, DOI 10.5151/chempro-15bmos-BMOS2013_20139416531