Dezembro 2013 vol. 1 num. 2 - Brazilian Meeting on Organic Synthesis 2013

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Borylation, Silylation, Fluorination and Fluoroalkylation

Hartwig, John F. ;

Abstract:

This lecture will present a combination of methodology and underlying principles addressing the functionalization of C-H bonds of arenes and alkanes with main group reagents and the fluorination and fluoroalkylation of arenes, heteroarenes, and organic halides. The development of reactions that regioselectively convert aromatic and aliphatic C-H bonds to aryl and alkyl borane and silane derivatives will be presented, along with reactions of these main group species to form a series of functionalized products. The development of reactions of aryl and heteroaryl halides that form fluoroarenes and fluoroalkylarenes also will be presented. The relationships between C-B, C-Si, C-F and C-Rf bond-forming processes will be discussed.

Abstract:

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Palavras-chave: C-H bond functionalization, Cross Coupling, Catalysis,

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DOI: 10.5151/chempro-15bmos-11-Hartwig_Speech_15th_BMOS-9.27.13

Referências bibliográficas
  • [1] 1 Mkhalid, I. A. I.; Barnard, J. H.; Marder, T. B.; Murphy, J. M.; Hartwig, J. F. Chem. Rev. 2010, 110, 890.
  • [2] 2 Simmons, E. M.; Hartwig, J. F. Nature 2012, 483, 70.
  • [3] 3 Morimoto, H.; Tsubogo, T.; Litvinas, N. D.; Hartwig, J. F. Angew. Chem. Int. Ed. 2011, 50, 379
Como citar:

Hartwig, John F.; "Borylation, Silylation, Fluorination and Fluoroalkylation", p. 325 . In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 2, Dezembro.2013. São Paulo: Blucher, 2013.
ISSN 2318-4043, DOI 10.5151/chempro-15bmos-11-Hartwig_Speech_15th_BMOS-9.27.13

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