Dezembro 2013 vol. 1 num. 2 - Brazilian Meeting on Organic Synthesis 2013

Abstract - Open Access.

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Electrochemical dimerization of benzyl chloride on a powder cathode of silver, graphite or silver-graphite mixture

Souza, Ronny F. M. ; Areias, Madalena C. C. ; Navarro, Marcelo ; Laurent, Michel ; Léonel, Eric ; Cachet-Vivier, Christine ; Bieber, Lothar W. ;

Abstract:

The main challenge in organic synthesis is the formation of new C-C bonds in order to construct more complex carbon skeletons in a defined arrangement. In contemporary electrochemical publications, such C-C couplings are still a minor subject. Herein we reported an application of a new electrochemical cell which uses graphite powder, silver powder or mix graphite/silver powder in the cathode cavity combined with an aqueous anolyte to promote the dimerization of benzyl chloride in good yield.

Abstract:

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Palavras-chave: cavity cell, benzyl halides, solvent-free,

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DOI: 10.5151/chempro-15bmos-BMOS2013_20137119933

Referências bibliográficas
  • [1] 1 Yoshida, J.; Katoaka, K.; Horcajada, R.; Nagaki, A. Chem. Rev. 2008, 108, 2265.
  • [2] 2 Areias, M. C. C.; Navarro, M.; Bieber, L. W.; Diniz, F. B.; Leonel, E.; Cachet-Vivier, C.; Nedelec, J. Y. Electrochim. Acta, 2008, 53, 6477.
  • [3] 3 Souza, R. F. M.; Souza, C. A.; Areias, M. C. C.; Cachet-Vivier, C.; Laurent, M.; Barhdadi, R.; Navarro, M.; Bieber, L. W. Electrochim. Acta, 2010, 56, 575.
  • [4] 4 Souza, R. F. M.; Areias, M. C. C.; Bieber, L. W.; Navarro, M. Green Chemistry, 2011, 13, 1118.
  • [5] 5 Souza, R. F. M.; Areias, M. C. C.; Bieber, L. W.; Navarro, M. RSC Advances: an international journal to further the chemical science, 2013, 3, 6526.
Como citar:

Souza, Ronny F. M.; Areias, Madalena C. C.; Navarro, Marcelo; Laurent, Michel; Léonel, Eric; Cachet-Vivier, Christine; Bieber, Lothar W.; "Electrochemical dimerization of benzyl chloride on a powder cathode of silver, graphite or silver-graphite mixture", p. 3 . In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 2, Dezembro.2013. São Paulo: Blucher, 2013.
ISSN 2318-4043, DOI 10.5151/chempro-15bmos-BMOS2013_20137119933

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