Dezembro 2013 vol. 1 num. 2 - Brazilian Meeting on Organic Synthesis 2013

Abstract - Open Access.

Idioma principal

Synthesis and Functions of Biomimetic Helical Polymers and Oligomers

Yashima, Eiji ;

Abstract:

Unique macromolecules and oligomers that fold into a preferred-handed single- or double-stranded helical conformation induced by chiral substituents covalently bonded to the main-chains or external chiral stimuli followed by memory of the helical chirality are presented. The direct observations of helical structures of artificial helical polymers by atomic force microscopy (AFM) will be also presented. A series of double helices composed of different components and sequences that exhibit specific functions, such as chirality sensing, chiral recognition, enantioselective asymmetric catalysis, and anisotropic spring-like motion are also described.

Abstract:

Download (PDF)

Palavras-chave: Helix, Chiral recognition, Supramolecules,

Palavras-chave:

DOI: 10.5151/chempro-15bmos-9-YASHIMA_Speech_15th_BMOS-1_Yashima

Referências bibliográficas
  • [1] 1 Yashima, E.; Maeda, K.; Iida, H.; Furusho, Y.; Nagai, K. Chem. Rev. 2009, 109, 6102.
  • [2] 2 Kumaki, J.; Sakurai, S.-i.; Yashima, E. Chem. Soc. Rev. 2009, 38, 737.
  • [3] 3 Furusho, Y.; Yashima, E. Macromol. Rapid Commun. 2011, 32, 136.
Como citar:

Yashima, Eiji; "Synthesis and Functions of Biomimetic Helical Polymers and Oligomers", p. 324 . In: In Blucher Chemistry Proceedings, São Paulo, v. 1, n. 2, Dezembro.2013. São Paulo: Blucher, 2013.
ISSN 2318-4043, DOI 10.5151/chempro-15bmos-9-YASHIMA_Speech_15th_BMOS-1_Yashima

últimos 30 dias | último ano | desde a publicação


downloads


visualizações


indexações